Appendix F
.
Storage of Chemicals

It is important to avoid storing incompatible chemicals together. In the list below, do not store chemicals in the left column together with chemicals in the right column.

.

This chemical is . . .

  

incompatible with this chemical:

.

I. acids

  

bases

.

A. nitric acid

  

metals, acetic acid sulfuric acid, sulfides, nitrites and other reducing agents, chromic acid and chromate, permanganates, flammable liquids.

.

B. oxalic acid

  

silver, mercury

.

C. sulfuric acid

  

metals, chlorates, perchlorates, permanganate, nitric acid

.

II. alkali and alkaline earth

  

  

.

metals and their carbides, hydrides,
hydroxides, oxides, peroxides

  

water, acids, halogenated organics oxidizing agents

.

III. ammonia

  

halogens, silver, mercury, sodium hypochlorite (bleach)

.

IV. carbon, activated

  

oxidizing agents*

.

V. hydrogen peroxide

  

metals and their salts

.

VI. inorganic azides

  

acids, heavy metals and their salts, oxidizing agents*

.

VII. inorganic cyanides

  

acids, strong bases

.

VIII. inorganic nitrates

  

acids, metals, nitrites, sulfur

.

IX. inorganic nitrites

  

acids, oxidizing agents*

.

X. inorganic sulfides

  

acids

.

XI. organic compounds

  

oxidizing agents*

.

A. acetylene and monosubstituted acetylenes (R-CCH)

  

halogens, Group 11 and 12 metals and their salts

.

B. organic acyl halides

  

bases, organic hydroxy compounds

.

C. organic anhydrides

  

bases, organic hydroxy compounds

.

D. organic halogen compounds

  

aluminum metal

.

E. organic nitro compounds

  

strong bases

.

XII. phosphorus (yellow)

  

oxygen, oxidizing agents*, strong bases

.

XIII. phosphorus pentoxide

  

water

.

XIV. powdered metals

  

acids, oxidizing agents*

.

* Oxidizing agents include chromates, dichromates, chromium (VI) oxide, halogens, hydrogen peroxide and peroxides, nitric acid, nitrates, perchlorates and chlorates, permanganates, and persulfates.

This table was adapted from Prudent Practices in the Laboratory, 1995. Additional information on chemical incompatibility and storage patterns is available in the annual Chemical and Biological Catalog Reference Manual published by Flinn Scientific, Inc.